|
|
(3S)-3-hydroxytetradecanoyl-CoA <=> 2-tetradecenoyl-CoA + H2O
|
4.2.1.17
enoyl-CoA hydratase
4.2.1.74
long-chain-enoyl-CoA hydratase
|
–
–
|
|
BRENDA:
BS2105
KEGG:
R04740
MetaCyc:
RXN-14273
SABIO-RK:
4396
|
|
|
|
(S)-3-hydroxydecanoyl-CoA <=> trans-2-decenoyl-CoA + H2O
|
4.2.1.17
enoyl-CoA hydratase
4.2.1.74
long-chain-enoyl-CoA hydratase
|
–
–
|
|
BRENDA:
BS2103
KEGG:
R04744
MetaCyc:
RXN-13616
SABIO-RK:
4400
|
|
|
|
acetyl-CoA + myristoyl-CoA <=> CoA + 3-ketohexadecanoyl-CoA
|
2.3.1.155
acetyl-CoA C-myristoyltransferase
2.3.1.16
acetyl-CoA C-acyltransferase
|
–
–
|
|
BRENDA:
BR29472
KEGG:
R03991
MetaCyc:
2.3.1.155-RXN;
RXN-16560
SABIO-RK:
3726
|
|
|
|
L-3-hydroxydodecanoyl-CoA + NAD+ <=> 3-oxododecanoyl-CoA + NADH + H+
|
1.1.1.211
long-chain-3-hydroxyacyl-CoA dehydrogenase
1.1.1.35
3-hydroxyacyl-CoA dehydrogenase
|
–
–
|
|
KEGG:
R04741
MetaCyc:
RXN-20676
|
|
|
|
hexanoyl-CoA + acetyl-CoA <=> 3-oxooctanoyl-CoA + CoA
|
2.3.1.155
acetyl-CoA C-myristoyltransferase
2.3.1.16
acetyl-CoA C-acyltransferase
|
–
–
|
|
BRENDA:
BS189545
KEGG:
R04747
MetaCyc:
RXN-14277
SABIO-RK:
4403
|
|
|
|
(3S)-3-hydroxyacyl-CoA <=> trans-2-enoyl-CoA + H2O
|
4.2.1.119
enoyl-CoA hydratase 2
4.2.1.134
very-long-chain (3R)-3-hydroxyacyl-CoA dehydratase
4.2.1.17
enoyl-CoA hydratase
4.2.1.74
long-chain-enoyl-CoA hydratase
|
–
–
–
–
|
|
BRENDA:
BR3387;
BR48986;
BS406348;
BS419277
KEGG:
R02685;
R09698
MetaCyc:
ENOYL-COA-HYDRAT-RXN;
RXN-19190;
RXN-7699
|
|
|
|
L-3-hydroxydodecanoyl-CoA <=> trans-2-dodecenoyl-CoA + H2O
|
4.2.1.17
enoyl-CoA hydratase
4.2.1.74
long-chain-enoyl-CoA hydratase
|
–
–
|
|
BRENDA:
BS2104
KEGG:
R04170
MetaCyc:
RXN-20675
SABIO-RK:
3890
|
|
|
|
acyl-CoA + NADP+ <=> trans-2-enoyl-CoA + NADPH + H+
|
1.3.1.38
trans-2-enoyl-CoA reductase (NADPH)
1.3.1.44
trans-2-enoyl-CoA reductase (NAD+)
1.3.1.8
acyl-CoA dehydrogenase (NADP+)
|
–
–
–
|
|
BRENDA:
BR36819
KEGG:
R00385;
R07162
MetaCyc:
ACYL-COA-DEHYDROGENASE-NADP+-RXN
|
|
|
|
butyryl-CoA + acetyl-CoA <=> 3-oxohexanoyl-CoA + CoA
|
2.3.1.155
acetyl-CoA C-myristoyltransferase
2.3.1.16
acetyl-CoA C-acyltransferase
2.3.1.9
acetyl-CoA C-acetyltransferase
|
–
–
–
|
|
BRENDA:
BS189544
KEGG:
R01177
MetaCyc:
RXN-12565
SABIO-RK:
1414
|
|
|
|
decanoyl-CoA + acetyl-CoA <=> 3-oxododecanoyl-CoA + CoA
|
2.3.1.155
acetyl-CoA C-myristoyltransferase
2.3.1.16
acetyl-CoA C-acyltransferase
|
–
–
|
|
BRENDA:
BS189547
KEGG:
R04742
MetaCyc:
RXN-14274
SABIO-RK:
4398
|
|
|
|
acyl-CoA + NADP+ <=> trans-2-enoyl-CoA + NADPH + H+
|
1.3.1.38
trans-2-enoyl-CoA reductase (NADPH)
1.3.1.44
trans-2-enoyl-CoA reductase (NAD+)
1.3.1.8
acyl-CoA dehydrogenase (NADP+)
|
–
–
–
|
|
BRENDA:
BR36819
KEGG:
R00385;
R07162
MetaCyc:
ACYL-COA-DEHYDROGENASE-NADP+-RXN
|
|
|
|
a_very-long-chain_(3R)-3-hydroxyacyl-CoA + NADP+ <=> a_very-long-chain_3-oxoacyl-CoA + NADPH + H+
|
1.1.1.330
very-long-chain 3-oxoacyl-CoA reductase
|
–
|
|
BRENDA:
BR50139
KEGG:
R10826
|
|
|
|
(3S)-3-hydroxyacyl-CoA + NAD+ <=> 3-oxoacyl-CoA + NADH + H+
|
1.1.1.211
long-chain-3-hydroxyacyl-CoA dehydrogenase
1.1.1.35
3-hydroxyacyl-CoA dehydrogenase
1.1.1.36
acetoacetyl-CoA reductase
1.1.1.M19
|
–
–
–
–
|
|
BRENDA:
BR29255;
BS370795;
BS394813
KEGG:
R01778
MetaCyc:
OHACYL-COA-DEHYDROG-RXN;
RXN-16133;
RXN66-485
|
|
|
|
(S)-3-hydroxyoctanoyl-CoA <=> 2-octenoyl-CoA + H2O
|
4.2.1.17
enoyl-CoA hydratase
4.2.1.74
long-chain-enoyl-CoA hydratase
|
–
–
|
|
BRENDA:
BS2102
KEGG:
R04746
MetaCyc:
RXN-20678
SABIO-RK:
4402
|
|
|
|
(3S)-hydroxyhexadecanoyl-CoA <=> trans-2-hexadecenoyl-CoA + H2O
|
4.2.1.17
enoyl-CoA hydratase
4.2.1.74
long-chain-enoyl-CoA hydratase
|
–
–
|
|
BRENDA:
BR451
KEGG:
R04738
MetaCyc:
LONG-CHAIN-ENOYL-COA-HYDRATASE-RXN;
RXN-14272
SABIO-RK:
4394
|
|
|
|
trans-2-decenoyl-CoA + NADPH <=> decanoyl-CoA + NADP+
|
1.3.1.38
trans-2-enoyl-CoA reductase (NADPH)
1.3.1.8
acyl-CoA dehydrogenase (NADP+)
|
–
–
|
|
BRENDA:
BS258527
KEGG:
R04753
SABIO-RK:
4409
|
|
|
|
octanoyl-CoA + acetyl-CoA <=> 3-oxodecanoyl-CoA + CoA
|
2.3.1.155
acetyl-CoA C-myristoyltransferase
2.3.1.16
acetyl-CoA C-acyltransferase
|
–
–
|
|
BRENDA:
BS189546
KEGG:
R03778
MetaCyc:
RXN-13617
SABIO-RK:
3537
|
|
|
|
(S)-3-hydroxyoctanoyl-CoA + NAD+ <=> 3-oxooctanoyl-CoA + NADH + H+
|
1.1.1.211
long-chain-3-hydroxyacyl-CoA dehydrogenase
1.1.1.35
3-hydroxyacyl-CoA dehydrogenase
|
–
–
|
|
BRENDA:
BS188060
KEGG:
R04745
MetaCyc:
RXN-20679
SABIO-RK:
4401
|
|
|
|
trans-2-dodecenoyl-CoA + NADPH <=> lauroyl-CoA + NADP+
|
1.3.1.10
enoyl-[acyl-carrier-protein] reductase (NADPH, Si-specific)
1.3.1.38
trans-2-enoyl-CoA reductase (NADPH)
1.3.1.39
enoyl-[acyl-carrier-protein] reductase (NADPH, Re-specific)
1.3.1.8
acyl-CoA dehydrogenase (NADP+)
|
–
–
–
–
|
|
BRENDA:
BS258634
KEGG:
R03856
SABIO-RK:
8000
|
|
|
|
lauroyl-CoA + acetyl-CoA <=> 3-oxotetradecanoyl-CoA + CoA
|
2.3.1.16
acetyl-CoA C-acyltransferase
|
–
|
|
KEGG:
R03858
MetaCyc:
RXN-14268
|
|
|
|
2-tetradecenoyl-CoA + NADPH <=> myristoyl-CoA + NADP+
|
1.3.1.38
trans-2-enoyl-CoA reductase (NADPH)
1.3.1.8
acyl-CoA dehydrogenase (NADP+)
|
–
–
|
|
BRENDA:
BS258642
KEGG:
R03989
|
|
|
|
palmitoyl-CoA + NADP+ <=> trans-2-hexadecenoyl-CoA + NADPH + H+
|
1.3.1.38
trans-2-enoyl-CoA reductase (NADPH)
1.3.1.8
acyl-CoA dehydrogenase (NADP+)
|
–
–
|
|
BRENDA:
BS258627
KEGG:
R01278
MetaCyc:
RXN-14194
SABIO-RK:
1494
|
|
|
|
behenoyl-CoA + NADP+ <=> trans-docos-2-enoyl-CoA + NADPH + H+
|
1.3.1.93
very-long-chain enoyl-CoA reductase
|
–
|
|
BRENDA:
BR50149
KEGG:
R10828
MetaCyc:
RXN-13307
|
|
|
|
acyl-CoA + acetyl-CoA <=> 3-oxoacyl-CoA + CoA
|
2.3.1.16
acetyl-CoA C-acyltransferase
|
–
|
|
BRENDA:
BR44009
KEGG:
R00391
MetaCyc:
RXN-20153
|
|
|
|
(S)-3-hydroxydecanoyl-CoA + NAD+ <=> 3-oxodecanoyl-CoA + NADH + H+
|
1.1.1.211
long-chain-3-hydroxyacyl-CoA dehydrogenase
1.1.1.35
3-hydroxyacyl-CoA dehydrogenase
|
–
–
|
|
BRENDA:
BS188068
KEGG:
R04743
MetaCyc:
RXN-12490
SABIO-RK:
4399
|
|
|
|
(3S)-3-hydroxytetradecanoyl-CoA + NAD+ <=> 3-oxotetradecanoyl-CoA + NADH + H+
|
1.1.1.211
long-chain-3-hydroxyacyl-CoA dehydrogenase
1.1.1.35
3-hydroxyacyl-CoA dehydrogenase
|
–
–
|
|
KEGG:
R04739
MetaCyc:
RXN-12507
SABIO-RK:
4395
|
|
|
|
palmitoyl-CoA + H2O <=> H+ + palmitate + CoA
|
2.3.1.16
acetyl-CoA C-acyltransferase
3.1.1.1
carboxylesterase
3.1.1.23
acylglycerol lipase
3.1.1.5
lysophospholipase
3.1.2
3.1.2.1
acetyl-CoA hydrolase
3.1.2.2
palmitoyl-CoA hydrolase
3.1.2.20
acyl-CoA hydrolase
3.1.2.22
palmitoyl[protein] hydrolase
3.1.2.25
phenylacetyl-CoA hydrolase
|
–
–
–
–
–
–
–
–
–
–
|
|
BRENDA:
BR48147;
BS115468
KEGG:
R01274;
R08174;
R09450
MetaCyc:
PALMITOYL-COA-HYDROLASE-RXN;
RXN-16395;
RXN-9624
SABIO-RK:
1490;
6573
|
|
|
|
behenoyl-CoA + malonyl-CoA <=> a_very-long-chain_3-oxoacyl-CoA + CO2 + CoA
|
2.3.1.199
very-long-chain 3-oxoacyl-CoA synthase
|
–
|
|
BRENDA:
BR50172
KEGG:
R10825
|
|
|
|
trans-2-hexenoyl-CoA + NADPH <=> hexanoyl-CoA + NADP+
|
1.3.1.10
enoyl-[acyl-carrier-protein] reductase (NADPH, Si-specific)
1.3.1.38
trans-2-enoyl-CoA reductase (NADPH)
1.3.1.44
trans-2-enoyl-CoA reductase (NAD+)
1.3.1.8
acyl-CoA dehydrogenase (NADP+)
|
–
–
–
–
|
|
BRENDA:
BS258524
KEGG:
R06985
SABIO-RK:
7658
|
|
|
|
2-octenoyl-CoA + NADPH <=> octanoyl-CoA + NADP+
|
1.3.1.10
enoyl-[acyl-carrier-protein] reductase (NADPH, Si-specific)
1.3.1.38
trans-2-enoyl-CoA reductase (NADPH)
1.3.1.8
acyl-CoA dehydrogenase (NADP+)
|
–
–
–
|
|
BRENDA:
BS258525
KEGG:
R03776
SABIO-RK:
8001;
8991
|
|
|
|
(S)-3-hydroxyhexanoyl-CoA + NAD+ <=> 3-oxohexanoyl-CoA + NADH + H+
|
1.1.1.211
long-chain-3-hydroxyacyl-CoA dehydrogenase
1.1.1.35
3-hydroxyacyl-CoA dehydrogenase
|
–
–
|
|
BRENDA:
BS188067
KEGG:
R04748
MetaCyc:
RXN-12570
SABIO-RK:
4404
|
|
|
|
a_very-long-chain_(3R)-3-hydroxyacyl-CoA <=> very-long-chain_(2E)-2-enoyl-CoA + H2O
|
4.2.1.134
very-long-chain (3R)-3-hydroxyacyl-CoA dehydratase
|
–
|
|
BRENDA:
BR50205
KEGG:
R10827
MetaCyc:
RXN-11750
|
|
|
|
(S)-3-hydroxyhexanoyl-CoA <=> trans-2-hexenoyl-CoA + H2O
|
4.2.1.150
short-chain-enoyl-CoA hydratase
4.2.1.17
enoyl-CoA hydratase
4.2.1.74
long-chain-enoyl-CoA hydratase
|
–
–
–
|
|
BRENDA:
BS2101
KEGG:
R04749
MetaCyc:
RXN-12567;
RXN-20677
SABIO-RK:
4405
|
|
|
|
(3S)-hydroxyhexadecanoyl-CoA + NAD+ <=> 3-ketohexadecanoyl-CoA + NADH + H+
|
1.1.1.211
long-chain-3-hydroxyacyl-CoA dehydrogenase
1.1.1.35
3-hydroxyacyl-CoA dehydrogenase
|
–
–
|
|
BRENDA:
BR50824
KEGG:
R04737
MetaCyc:
1.1.1.211-RXN;
RXN-14271
SABIO-RK:
4393
|
|
|
|
palmitoyl-CoA + H2O <=> H+ + palmitate + CoA
|
2.3.1.16
acetyl-CoA C-acyltransferase
3.1.1.1
carboxylesterase
3.1.1.23
acylglycerol lipase
3.1.1.5
lysophospholipase
3.1.2
3.1.2.1
acetyl-CoA hydrolase
3.1.2.2
palmitoyl-CoA hydrolase
3.1.2.20
acyl-CoA hydrolase
3.1.2.22
palmitoyl[protein] hydrolase
3.1.2.25
phenylacetyl-CoA hydrolase
|
–
–
–
–
–
–
–
–
–
–
|
|
BRENDA:
BR48147;
BS115468
KEGG:
R01274;
R08174;
R09450
MetaCyc:
PALMITOYL-COA-HYDROLASE-RXN;
RXN-16395;
RXN-9624
SABIO-RK:
1490;
6573
|
|